Most Famous Couples Of The ’90s

7.Brad Pitt And Gwyneth Paltrow Hollywood royalty in every sense, Brad Pitt and Gwyneth Paltrow were the golden couple before Brangelina was even a thing. Pitt, the heartthrob starring in hits like Seven and Fight Club, and Paltrow, a rising star with her ethereal beauty and acting chops, seemed like a match made in heaven. Their red carpet appearances and subsequent breakup were covered breathlessly by the media, cementing their status as an unmissable '90s love story.